T36 Summary for the Sections 1 to 35
If one defines temperature as a fundamental unit of physics, as in section 15 of this treatise, then the following values are relativistically invariant:
- temperature T n( and temperature changes )
- pressure P n( and pressure changes )
- particle number N j and amount of substance n j=j N / NA
- thermodynamic efficiency
- heat capacity ratio kappa = CP / CV
The following values are transformed by multiplying by the root factor:
- volume V n( and volume changes )
- the Boltzmann constant k nand the universal gas constant R
- average velocity of the particles relative to the center of mass
- heat quantity Q n( and their changes )
- internal energy U n( and their changes )
- volume work P · V n( and their changes )
- enthalpy H n( and their changes )
- entropy S ( and their changes )
- molar heat capacity CV and CP
- molrelated melting- and evaporation energies
The following values are transformed by dividing by the root factor:
- total energy E jof the gas
- particle density
There is no simple transformation in the sense of section 2 for the following process variable:
- peformed work jW
Taking into account these transformations, all the essential relationships of thermodynamics persist !
The following relationships are invariant:
- the first law of thermodynamics, thus mmmjmm ∆E j= j∆Q j+ ∆W
- the second law of thermodynamics, thus mnni ∆S j≥ j0 in a closed system
- for ideal gases mmmm CP j– CV j=j R
- for ideal gases mmm m P · V j= n · R · T j= jN · k · T
- for the entropy mmmmmm dS · T j=j dQ mm and mm Sj=j k · ln(Ω)
For non-relativistic ideal gases we further have the invariant relationships![]()
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It should be noted that we have not assumed the validity of these relationships for a fast moving observer in order to derive the transformation rules ! We only assumed that such a transformation exists for T , and in addition we have chosen a definition of temperature within the limiting conditions of k' · T' n= k · T · √ so that temperature is relativistically invariant. Most of the results were established even before this decision ( see section 33 ).
Planck, Einstein, Hasenöhrl and von Mosengeil made no errors (unlike many others) in the derivation of their results. They just decided that jk' = k should apply, and then they derived the other results in a logically correct way.
Avramov, however, made the better choice !
